A great farming spot for this is where you encounter molotov enemies for the very first time. This is in an early story mission called “The Home Fires Burn”, taking place in the Bayou. It’s the second story mission, so very early in the game.
At the start of the mission make sure you pick up a weak pistol and keep it for later. After Finding Baka an enemy will throw a molotov at you and you see a tutorial prompt on how to use molotovs. Hide behind cover and one of the enemies on the right will always throw a Molotov at you. It usually takes him 20 seconds to throw it. He will shout “Throwing Molotov” or “Firebomb” or “Fire from the Sky” when he is about to throw it – that’s when you must shoot him with the pistol. It’s important you use a low-damage pistol, otherwise your weapon might kill him. If you time it right he will drop the molotov and burn himself.
Run down to the other enemies and let them kill you (don’t use checkpoint restart, it may not track progress properly!). Repeat this 10 times. If something goes wrong always let the enemies kill you.
There are limited opportunities for this trophy / achievement. If you miss this opportunity I suggest you keep this for last and do it in a new game (luckily it’s near the start of the game).
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